Ä-conservation in the dissociation of singlet ketene

Axel Mellinger; Mclonie A. Hall; Elisabeth A. Wade; G. Bradley Moore

Ä-conservation in the dissociation of singlet ketene

Axel Mellinger, Mclonie A. Hall, Elisabeth A. Wade, G. Bradley Moore

Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The effect of K-conservation on the photodissociation of ketene has been investigated. Rate constants and photofragment excitation (PHOFEX) spectra have been calculated using phase space theory (PST) in a helicity basis. While the effect of K-conservation on rate constants is relatively subtle, PHOFEX spectra with state-selected reactant molecules appear to provide a feasible way to experimentally resolve the question of K-conservation.

Original language	English
Pages (from-to)	465-468
Number of pages	4
Journal	Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics
Volume	101
Issue number	3
State	Published - 1997

Keywords

Chemical kinetics
Photochemistry
Reaction dynamics

Cite this

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title = "{\"A}-conservation in the dissociation of singlet ketene",

abstract = "The effect of K-conservation on the photodissociation of ketene has been investigated. Rate constants and photofragment excitation (PHOFEX) spectra have been calculated using phase space theory (PST) in a helicity basis. While the effect of K-conservation on rate constants is relatively subtle, PHOFEX spectra with state-selected reactant molecules appear to provide a feasible way to experimentally resolve the question of K-conservation.",

keywords = "Chemical kinetics, Photochemistry, Reaction dynamics",

author = "Axel Mellinger and Hall, {Mclonie A.} and Wade, {Elisabeth A.} and {Bradley Moore}, G.",

year = "1997",

language = "English",

volume = "101",

pages = "465--468",

journal = "Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics",

issn = "0940-483X",

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TY - JOUR

T1 - Ä-conservation in the dissociation of singlet ketene

AU - Mellinger, Axel

AU - Hall, Mclonie A.

AU - Wade, Elisabeth A.

AU - Bradley Moore, G.

PY - 1997

Y1 - 1997

N2 - The effect of K-conservation on the photodissociation of ketene has been investigated. Rate constants and photofragment excitation (PHOFEX) spectra have been calculated using phase space theory (PST) in a helicity basis. While the effect of K-conservation on rate constants is relatively subtle, PHOFEX spectra with state-selected reactant molecules appear to provide a feasible way to experimentally resolve the question of K-conservation.

AB - The effect of K-conservation on the photodissociation of ketene has been investigated. Rate constants and photofragment excitation (PHOFEX) spectra have been calculated using phase space theory (PST) in a helicity basis. While the effect of K-conservation on rate constants is relatively subtle, PHOFEX spectra with state-selected reactant molecules appear to provide a feasible way to experimentally resolve the question of K-conservation.

KW - Chemical kinetics

KW - Photochemistry

KW - Reaction dynamics

UR - http://www.scopus.com/inward/record.url?scp=0005332878&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0005332878

SN - 0940-483X

VL - 101

SP - 465

EP - 468

JO - Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics

JF - Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics

IS - 3

ER -

Ä-conservation in the dissociation of singlet ketene

Abstract

Keywords

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