TY - JOUR
T1 - A review on the electrocatalytic dissociation of water over stainless steel
T2 - Hydrogen and oxygen evolution reactions
AU - Raza, A.
AU - Deen, K. M.
AU - Asselin, E.
AU - Haider, W.
N1 - Funding Information:
This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors.
Publisher Copyright:
© 2022 Elsevier Ltd
PY - 2022/6
Y1 - 2022/6
N2 - For the hydrogen economy to be viable, new, and efficient production techniques are of prime importance. Water electrolysis offers high production of hydrogen but due to slow reaction rates on many electrode surfaces, electrocatalysts are needed. However effective electrocatalysts, such as platinum and rhenium, may be impractical for economic operation. Therefore, research in this area has been focused on finding materials that can replace these expensive electrocatalysts. The electrocatalytic behaviour of stainless steel towards water dissociation is presented. The use of two widely available and comparatively inexpensive stainless steels i.e., 304 and 316L, in a variety of forms, i.e., mesh, solid electrode, and adsorbed nanoparticles is discussed. Results of microscopic characterization are compiled to illustrate how surface modification of these substrates affects their electrocatalytic ability. The crystallographic orientations i.e. (111) and (220) in the microstructure of stainless steel are believed to be effective in catalytic dissociation of H2O. The catalytic activity and long-term stability measurements of stainless steels have yielded results similar to or sometimes better than-those of the noble electrocatalysts. The review briefly captures the current progress in HER and OER electrocatalysis on stainless steels and highlights the possible research solutions to overcome existing challenges i.e., lack of active centers, the surface modification needed, poisoning of active species and an overall low stability, the solution to which could make stainless steel a viable replacement for the precious metals electrocatalysts.
AB - For the hydrogen economy to be viable, new, and efficient production techniques are of prime importance. Water electrolysis offers high production of hydrogen but due to slow reaction rates on many electrode surfaces, electrocatalysts are needed. However effective electrocatalysts, such as platinum and rhenium, may be impractical for economic operation. Therefore, research in this area has been focused on finding materials that can replace these expensive electrocatalysts. The electrocatalytic behaviour of stainless steel towards water dissociation is presented. The use of two widely available and comparatively inexpensive stainless steels i.e., 304 and 316L, in a variety of forms, i.e., mesh, solid electrode, and adsorbed nanoparticles is discussed. Results of microscopic characterization are compiled to illustrate how surface modification of these substrates affects their electrocatalytic ability. The crystallographic orientations i.e. (111) and (220) in the microstructure of stainless steel are believed to be effective in catalytic dissociation of H2O. The catalytic activity and long-term stability measurements of stainless steels have yielded results similar to or sometimes better than-those of the noble electrocatalysts. The review briefly captures the current progress in HER and OER electrocatalysis on stainless steels and highlights the possible research solutions to overcome existing challenges i.e., lack of active centers, the surface modification needed, poisoning of active species and an overall low stability, the solution to which could make stainless steel a viable replacement for the precious metals electrocatalysts.
KW - Butler-volmer equation
KW - Electrocatalysis
KW - Hydrogen evolution reaction
KW - Oxygen evolution reaction
KW - Surface modification
KW - Water splitting
UR - http://www.scopus.com/inward/record.url?scp=85127060524&partnerID=8YFLogxK
U2 - 10.1016/j.rser.2022.112323
DO - 10.1016/j.rser.2022.112323
M3 - Review article
AN - SCOPUS:85127060524
VL - 161
JO - Renewable and Sustainable Energy Reviews
JF - Renewable and Sustainable Energy Reviews
SN - 1364-0321
M1 - 112323
ER -