Assembly of metal-anion arrays within Dion-Jacobson-type perovskite hosts

Thomas A. Kodenkandath; Marilena L. Viciu; Xiao Zhang; Jessica A. Sims; Erin W. Gilbert; François Xavier Augrain; Jean Noël Chotard; Gabriel A. Caruntu; Leonard Spinu; Weilie L. Zhou; John B. Wiley

Assembly of metal-anion arrays within Dion-Jacobson-type perovskite hosts

Thomas A. Kodenkandath, Marilena L. Viciu, Xiao Zhang, Jessica A. Sims, Erin W. Gilbert, François Xavier Augrain, Jean Noël Chotard, Gabriel A. Caruntu, Leonard Spinu, Weilie L. Zhou, John B. Wiley

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The construction of metal-anion arrays within Dion-Jacobson-type (DJ) perovskites was studied. A variety of hosts readily react with CuCl₂ to produce compounds of the form (CuCl)[A′_n-1(M, M′)_nO_3n+1] (A′ = alkaline earth, rare earth or Bi; M/M′ = Nb, Ta, and/orTi; n = 2, 3). In contrast, CuBr₂ only reacts with some of these hosts; this difference relative to the chloride may simply be a size effect. The formation of metal-anion arrays with other transition metals has also been examined. (FeCl)LaNb₂O₇ can be readily prepared from FeCl₂, while reactions with FeBr₂ and NiCl₂ under similar reaction conditions result in compounds of the form M_0.5LaNb₂O₇ (M = Fe, Ni). The reductive intercalation of lithium and sodium into (CuCl)LaNb₂O₇ was also examined and was found to produce new compounds that have a large layer expansion.

Original language	English
Pages (from-to)	GG851-GG856
Journal	Materials Research Society Symposium - Proceedings
Volume	658
State	Published - 2001

Cite this

@article{83016c0bdee5483db7cff04efe4035e5,

title = "Assembly of metal-anion arrays within Dion-Jacobson-type perovskite hosts",

abstract = "The construction of metal-anion arrays within Dion-Jacobson-type (DJ) perovskites was studied. A variety of hosts readily react with CuCl2 to produce compounds of the form (CuCl)[A′n-1(M, M′)nO3n+1] (A′ = alkaline earth, rare earth or Bi; M/M′ = Nb, Ta, and/orTi; n = 2, 3). In contrast, CuBr2 only reacts with some of these hosts; this difference relative to the chloride may simply be a size effect. The formation of metal-anion arrays with other transition metals has also been examined. (FeCl)LaNb2O7 can be readily prepared from FeCl2, while reactions with FeBr2 and NiCl2 under similar reaction conditions result in compounds of the form M0.5LaNb2O7 (M = Fe, Ni). The reductive intercalation of lithium and sodium into (CuCl)LaNb2O7 was also examined and was found to produce new compounds that have a large layer expansion.",

author = "Kodenkandath, {Thomas A.} and Viciu, {Marilena L.} and Xiao Zhang and Sims, {Jessica A.} and Gilbert, {Erin W.} and Augrain, {Fran{\c c}ois Xavier} and Chotard, {Jean No{\"e}l} and Caruntu, {Gabriel A.} and Leonard Spinu and Zhou, {Weilie L.} and Wiley, {John B.}",

note = "Funding Information: The authors gratefully acknowledge the support provided by the National Science Foundation (DMR-9983591) and the Department of Defense (DARPA MDA972-97-1-0003).",

year = "2001",

language = "English",

volume = "658",

pages = "GG851--GG856",

journal = "Materials Research Society Symposium - Proceedings",

issn = "0272-9172",

}

TY - JOUR

T1 - Assembly of metal-anion arrays within Dion-Jacobson-type perovskite hosts

AU - Kodenkandath, Thomas A.

AU - Viciu, Marilena L.

AU - Zhang, Xiao

AU - Sims, Jessica A.

AU - Gilbert, Erin W.

AU - Augrain, François Xavier

AU - Chotard, Jean Noël

AU - Caruntu, Gabriel A.

AU - Spinu, Leonard

AU - Zhou, Weilie L.

AU - Wiley, John B.

N1 - Funding Information: The authors gratefully acknowledge the support provided by the National Science Foundation (DMR-9983591) and the Department of Defense (DARPA MDA972-97-1-0003).

PY - 2001

Y1 - 2001

N2 - The construction of metal-anion arrays within Dion-Jacobson-type (DJ) perovskites was studied. A variety of hosts readily react with CuCl2 to produce compounds of the form (CuCl)[A′n-1(M, M′)nO3n+1] (A′ = alkaline earth, rare earth or Bi; M/M′ = Nb, Ta, and/orTi; n = 2, 3). In contrast, CuBr2 only reacts with some of these hosts; this difference relative to the chloride may simply be a size effect. The formation of metal-anion arrays with other transition metals has also been examined. (FeCl)LaNb2O7 can be readily prepared from FeCl2, while reactions with FeBr2 and NiCl2 under similar reaction conditions result in compounds of the form M0.5LaNb2O7 (M = Fe, Ni). The reductive intercalation of lithium and sodium into (CuCl)LaNb2O7 was also examined and was found to produce new compounds that have a large layer expansion.

AB - The construction of metal-anion arrays within Dion-Jacobson-type (DJ) perovskites was studied. A variety of hosts readily react with CuCl2 to produce compounds of the form (CuCl)[A′n-1(M, M′)nO3n+1] (A′ = alkaline earth, rare earth or Bi; M/M′ = Nb, Ta, and/orTi; n = 2, 3). In contrast, CuBr2 only reacts with some of these hosts; this difference relative to the chloride may simply be a size effect. The formation of metal-anion arrays with other transition metals has also been examined. (FeCl)LaNb2O7 can be readily prepared from FeCl2, while reactions with FeBr2 and NiCl2 under similar reaction conditions result in compounds of the form M0.5LaNb2O7 (M = Fe, Ni). The reductive intercalation of lithium and sodium into (CuCl)LaNb2O7 was also examined and was found to produce new compounds that have a large layer expansion.

UR - http://www.scopus.com/inward/record.url?scp=0035558272&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0035558272

VL - 658

SP - GG851-GG856

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

SN - 0272-9172

ER -

Assembly of metal-anion arrays within Dion-Jacobson-type perovskite hosts

Abstract

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