Cationic distribution oil CuxCo3-xO4 (O<x<1)

K. Petrov, V. Petkov, M. Mikhov

Research output: Contribution to journalArticlepeer-review

7 Scopus citations


The cationic distribution of CuxCO3-xO4 (o<x<1) prepared by thermal decomposition of layered CUyCo2-y(OH)3NO3 (o<y< 2 3) has been studied by magnetic and X-ray diffraction methods. It is shown that the final oxide product, formed without long-range diffusion transport, is a metastable phase with a stressed crystal lattice and a cationic distribution corresponding to that of a mixed spinel.

Original languageEnglish
Pages (from-to)511-519
Number of pages9
JournalMaterials Chemistry and Physics
Issue number6
StatePublished - Dec 1986


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