Copper and manganese sulfanilate hydrates

Brian J. Gunderman, Philip J. Squattrito, Surendra N. Dubey

Research output: Contribution to journalArticlepeer-review

25 Scopus citations

Abstract

The title compounds, bis(4-aminobenzenesulfonato)-diaquacopper(II) dihydrate, [Cu(C6H6NO3S)2(H2O) 2].-2H2O, and bis(4-aminobenzenesulfonato)diaquamanganese(II), [Mn(C6H6NO3S)2(H2O) 2], have structures in which the sulfanilate anions are arranged in layers with the functional groups directed towards adjacent layers. Between these slabs are the metal cations and water molecules. The Cu atom sits in a tetragonally distorted octahedron, with short contacts to two amine N atoms and two water molecules. Two sulfonate O atoms provide the longer interactions. The other water molecules are anchored by hydrogen bonds to the sulfonate groups. The Mn atom also displays a tetragonal distortion of its octahedral coordination to two sulfonate O atoms, two water molecules and, at the elongated vertices, two amine N atoms. The manganese salt contains no free water molecules. Both structures differ from those of the reported cobalt and zinc salts.

Original languageEnglish
Pages (from-to)1131-1134
Number of pages4
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number5
DOIs
StatePublished - May 15 1996

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