TY - JOUR
T1 - Diaquabis(4-amino-3-methyl -4,5-dihydro-1H-1,2,4-triazole-5-thione) nickel(II) nitrate
T2 - A sulfur-nitrogen chelate
AU - Sen, Ashok K.
AU - Dubey, Surendra N.
AU - Squattrito, Phillip J.
PY - 1996/1/1
Y1 - 1996/1/1
N2 - The title compound, [Ni(C3H6N4S)2(H2O)2](NO3)2, is an octahedral complex of nickel(II) in which two triazole ligands are coordinated in a bidentate fashion through the amine and thione substituents. The coordination sphere has the two S atoms trans with respect to each other, while the N atoms and two water molecules are ligated in cis positions. The Ni-S and Ni-N bond lengths in the chelate are consistent with those in similar octahedral nickel complexes. The geometry of the complexed triazole moiety is not substantially different from that of the free molecule.
AB - The title compound, [Ni(C3H6N4S)2(H2O)2](NO3)2, is an octahedral complex of nickel(II) in which two triazole ligands are coordinated in a bidentate fashion through the amine and thione substituents. The coordination sphere has the two S atoms trans with respect to each other, while the N atoms and two water molecules are ligated in cis positions. The Ni-S and Ni-N bond lengths in the chelate are consistent with those in similar octahedral nickel complexes. The geometry of the complexed triazole moiety is not substantially different from that of the free molecule.
UR - http://www.scopus.com/inward/record.url?scp=0030124034&partnerID=8YFLogxK
U2 - 10.1107/S010827019501496X
DO - 10.1107/S010827019501496X
M3 - Article
AN - SCOPUS:0030124034
SN - 0108-2701
VL - 52
SP - 865
EP - 868
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - Pt 4
ER -