Electrical properties of poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) blended with carbon nanotubes

Avtar Batth; Anja Mueller; Leela Rakesh; Axel Mellinger

doi:10.1109/CEIDP.2012.6378714

Electrical properties of poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) blended with carbon nanotubes

Avtar Batth, Anja Mueller, Leela Rakesh, Axel Mellinger

Research output: Contribution to journal › Conference article › peer-review

5 Scopus citations

Abstract

The composites of PVDF-HFP with various low concentrations (0-0.08 wt%) of single-walled carbon nanotubes (SWNTs) were prepared via solution casting and melt pressing, and were investigated for their enhanced dielectric and piezoelectric properties. It is found that the piezoelectric response increases by a factor of 1.5-3 over the pristine material for a 0.02 wt. % SWNT concentration in the polymer and decreases for higher concentrations. The principal reason for this optimal concentration is the solubility limit of SWNTs, as they are well dispersed up to 0.02 wt.% but become clustered for higher concentrations. Infrared spectroscopy and x-ray diffraction were used to reveal the interaction between the nanotube and polymeric phases. This analysis indicates that SWNTs content causes an increase in the piezoelectric β phase and a corresponding rise of the remanent polarization.

Original language	English
Article number	6378714
Pages (from-to)	28-31
Number of pages	4
Journal	Annual Report - Conference on Electrical Insulation and Dielectric Phenomena, CEIDP
DOIs	https://doi.org/10.1109/CEIDP.2012.6378714
State	Published - 2012
Event	2012 IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2012 - Montreal, QC, Canada Duration: Oct 14 2012 → Oct 17 2012

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title = "Electrical properties of poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) blended with carbon nanotubes",

abstract = "The composites of PVDF-HFP with various low concentrations (0-0.08 wt%) of single-walled carbon nanotubes (SWNTs) were prepared via solution casting and melt pressing, and were investigated for their enhanced dielectric and piezoelectric properties. It is found that the piezoelectric response increases by a factor of 1.5-3 over the pristine material for a 0.02 wt. % SWNT concentration in the polymer and decreases for higher concentrations. The principal reason for this optimal concentration is the solubility limit of SWNTs, as they are well dispersed up to 0.02 wt.% but become clustered for higher concentrations. Infrared spectroscopy and x-ray diffraction were used to reveal the interaction between the nanotube and polymeric phases. This analysis indicates that SWNTs content causes an increase in the piezoelectric β phase and a corresponding rise of the remanent polarization.",

author = "Avtar Batth and Anja Mueller and Leela Rakesh and Axel Mellinger",

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journal = "Annual Report - Conference on Electrical Insulation and Dielectric Phenomena, CEIDP",

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note = "null ; Conference date: 14-10-2012 Through 17-10-2012",

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T1 - Electrical properties of poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) blended with carbon nanotubes

AU - Batth, Avtar

AU - Mueller, Anja

AU - Rakesh, Leela

AU - Mellinger, Axel

PY - 2012

Y1 - 2012

N2 - The composites of PVDF-HFP with various low concentrations (0-0.08 wt%) of single-walled carbon nanotubes (SWNTs) were prepared via solution casting and melt pressing, and were investigated for their enhanced dielectric and piezoelectric properties. It is found that the piezoelectric response increases by a factor of 1.5-3 over the pristine material for a 0.02 wt. % SWNT concentration in the polymer and decreases for higher concentrations. The principal reason for this optimal concentration is the solubility limit of SWNTs, as they are well dispersed up to 0.02 wt.% but become clustered for higher concentrations. Infrared spectroscopy and x-ray diffraction were used to reveal the interaction between the nanotube and polymeric phases. This analysis indicates that SWNTs content causes an increase in the piezoelectric β phase and a corresponding rise of the remanent polarization.

AB - The composites of PVDF-HFP with various low concentrations (0-0.08 wt%) of single-walled carbon nanotubes (SWNTs) were prepared via solution casting and melt pressing, and were investigated for their enhanced dielectric and piezoelectric properties. It is found that the piezoelectric response increases by a factor of 1.5-3 over the pristine material for a 0.02 wt. % SWNT concentration in the polymer and decreases for higher concentrations. The principal reason for this optimal concentration is the solubility limit of SWNTs, as they are well dispersed up to 0.02 wt.% but become clustered for higher concentrations. Infrared spectroscopy and x-ray diffraction were used to reveal the interaction between the nanotube and polymeric phases. This analysis indicates that SWNTs content causes an increase in the piezoelectric β phase and a corresponding rise of the remanent polarization.

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JO - Annual Report - Conference on Electrical Insulation and Dielectric Phenomena, CEIDP

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Y2 - 14 October 2012 through 17 October 2012

ER -

Electrical properties of poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) blended with carbon nanotubes

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