Fullerene-coated beads as reusable catalysts

Anton W. Jensen; Coreen Daniels

doi:10.1021/jo025926z

Fullerene-coated beads as reusable catalysts

Anton W. Jensen, Coreen Daniels

https://www.cmich.edu/academics/colleges/college-science-engineering/departments-schools/chemistry-and-biochemistry

Research output: Contribution to journal › Article › peer-review

64 Scopus citations

Abstract

New heterogeneous catalysts that use oxygen and light to generate singlet oxygen (102) have been prepared. The catalysts facilitate various types of singlet oxygenation reactions including the Ene reaction, the Diels-Alder reaction, and others. The catalysts are made by stirring a heterogeneous mixture of fullerene-C₆₀(dissolved in toluene) with aminomethylated poly(styrene-co-divinylbenzene) beads. Also, catalysts for aqueous photooxidations are made by reacting the initial catalysts with poly(allylamine) to create an outer layer that is more hydrophilic.

Original language	English
Pages (from-to)	207-210
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	68
Issue number	2
DOIs	https://doi.org/10.1021/jo025926z
State	Published - Jan 24 2003

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10.1021/jo025926z

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abstract = "New heterogeneous catalysts that use oxygen and light to generate singlet oxygen (102) have been prepared. The catalysts facilitate various types of singlet oxygenation reactions including the Ene reaction, the Diels-Alder reaction, and others. The catalysts are made by stirring a heterogeneous mixture of fullerene-C60(dissolved in toluene) with aminomethylated poly(styrene-co-divinylbenzene) beads. Also, catalysts for aqueous photooxidations are made by reacting the initial catalysts with poly(allylamine) to create an outer layer that is more hydrophilic.",

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Fullerene-coated beads as reusable catalysts

Abstract

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