Fullerene-coated beads as reusable catalysts

Anton W. Jensen, Coreen Daniels

Research output: Contribution to journalArticlepeer-review

63 Scopus citations

Abstract

New heterogeneous catalysts that use oxygen and light to generate singlet oxygen (102) have been prepared. The catalysts facilitate various types of singlet oxygenation reactions including the Ene reaction, the Diels-Alder reaction, and others. The catalysts are made by stirring a heterogeneous mixture of fullerene-C60(dissolved in toluene) with aminomethylated poly(styrene-co-divinylbenzene) beads. Also, catalysts for aqueous photooxidations are made by reacting the initial catalysts with poly(allylamine) to create an outer layer that is more hydrophilic.

Original languageEnglish
Pages (from-to)207-210
Number of pages4
JournalJournal of Organic Chemistry
Volume68
Issue number2
DOIs
StatePublished - Jan 24 2003

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