TY - JOUR
T1 - Hexaaquacobalt(II) bis(2-aminotoluene-4-sulfonate)
AU - Gunderman, Brian J.
AU - Dubey, Surendra N.
AU - Squattrito, Philip J.
PY - 1997/1/15
Y1 - 1997/1/15
N2 - The title compound, [Co(H2O)6](C7H8NO3S) 2, has a structure built of segregated layers of hexaaquacobalt(II) cations and 2-aminotoluene-4-sulfonate anions. The Co atom is in a fairly regular octahedral coordination environment of water molecules [Co-O range 2.046(3)-2.111 (3) Å]. The anions are arranged with the sulfonate groups directed to opposite faces of the layer in an alternating fashion. The layers are held together by a series of O-H⋯O hydrogen bonds between the water molecules and sulfonate O atoms [H⋯O range 1.89 (4)-2-10 (4) Å]. The Mn and Zn salts are isostructural. These features are similar to those of other divalent metal organosulfonate salts.
AB - The title compound, [Co(H2O)6](C7H8NO3S) 2, has a structure built of segregated layers of hexaaquacobalt(II) cations and 2-aminotoluene-4-sulfonate anions. The Co atom is in a fairly regular octahedral coordination environment of water molecules [Co-O range 2.046(3)-2.111 (3) Å]. The anions are arranged with the sulfonate groups directed to opposite faces of the layer in an alternating fashion. The layers are held together by a series of O-H⋯O hydrogen bonds between the water molecules and sulfonate O atoms [H⋯O range 1.89 (4)-2-10 (4) Å]. The Mn and Zn salts are isostructural. These features are similar to those of other divalent metal organosulfonate salts.
UR - http://www.scopus.com/inward/record.url?scp=0030831453&partnerID=8YFLogxK
U2 - 10.1107/S0108270196011419
DO - 10.1107/S0108270196011419
M3 - Article
AN - SCOPUS:0030831453
SN - 0108-2701
VL - 53
SP - 17
EP - 19
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 1
ER -