Molecular structure of Al0.916Cr0.084(acac)3

Bradley D. Fahlman, Simon G. Bott, Andrew R. Barron

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

The molecular structure of a solid solution of Al(acac)3 and Cr(acac)3 has been determined. The Al:Cr ratio as determined by refinement of occupancy and anisotropic displacement parameters was determined to be 91.6:8.4%. The unit cell parameters for Al0.916Cr0.084(acac)3 are smaller and the M - O distances are intermediate compared to those in the pure compounds, Crystal data: monoclinic, P21/c, a = 13.989(3), b = 7.539(2), c = 16.307(3) Å, β= 98.82(3)°, V = 1699.6(6), Z = 4.

Original languageEnglish
Pages (from-to)65-67
Number of pages3
JournalJournal of Chemical Crystallography
Volume30
Issue number1
DOIs
StatePublished - Jan 2000

Keywords

  • Acetylacetonate
  • Aluminum
  • Chromium
  • Disorder
  • Solid solution

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