Molecular structure of Al0.916Cr0.084(acac)3

Bradley D. Fahlman; Simon G. Bott; Andrew R. Barron

doi:10.1023/A:1009554301560

Molecular structure of Al_0.916Cr_0.084(acac)₃

Bradley D. Fahlman, Simon G. Bott, Andrew R. Barron

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7 Scopus citations

Abstract

The molecular structure of a solid solution of Al(acac)₃ and Cr(acac)₃ has been determined. The Al:Cr ratio as determined by refinement of occupancy and anisotropic displacement parameters was determined to be 91.6:8.4%. The unit cell parameters for Al_0.916Cr_0.084(acac)₃ are smaller and the M - O distances are intermediate compared to those in the pure compounds, Crystal data: monoclinic, P2₁/c, a = 13.989(3), b = 7.539(2), c = 16.307(3) Å, β= 98.82(3)°, V = 1699.6(6), Z = 4.

Original language	English
Pages (from-to)	65-67
Number of pages	3
Journal	Journal of Chemical Crystallography
Volume	30
Issue number	1
DOIs	https://doi.org/10.1023/A:1009554301560
State	Published - Jan 2000

Keywords

Acetylacetonate
Aluminum
Chromium
Disorder
Solid solution

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title = "Molecular structure of Al0.916Cr0.084(acac)3",

abstract = "The molecular structure of a solid solution of Al(acac)3 and Cr(acac)3 has been determined. The Al:Cr ratio as determined by refinement of occupancy and anisotropic displacement parameters was determined to be 91.6:8.4%. The unit cell parameters for Al0.916Cr0.084(acac)3 are smaller and the M - O distances are intermediate compared to those in the pure compounds, Crystal data: monoclinic, P21/c, a = 13.989(3), b = 7.539(2), c = 16.307(3) {\AA}, β= 98.82(3)°, V = 1699.6(6), Z = 4.",

keywords = "Acetylacetonate, Aluminum, Chromium, Disorder, Solid solution",

author = "Fahlman, {Bradley D.} and Bott, {Simon G.} and Barron, {Andrew R.}",

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TY - JOUR

T1 - Molecular structure of Al0.916Cr0.084(acac)3

AU - Fahlman, Bradley D.

AU - Bott, Simon G.

AU - Barron, Andrew R.

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PY - 2000/1

Y1 - 2000/1

N2 - The molecular structure of a solid solution of Al(acac)3 and Cr(acac)3 has been determined. The Al:Cr ratio as determined by refinement of occupancy and anisotropic displacement parameters was determined to be 91.6:8.4%. The unit cell parameters for Al0.916Cr0.084(acac)3 are smaller and the M - O distances are intermediate compared to those in the pure compounds, Crystal data: monoclinic, P21/c, a = 13.989(3), b = 7.539(2), c = 16.307(3) Å, β= 98.82(3)°, V = 1699.6(6), Z = 4.

AB - The molecular structure of a solid solution of Al(acac)3 and Cr(acac)3 has been determined. The Al:Cr ratio as determined by refinement of occupancy and anisotropic displacement parameters was determined to be 91.6:8.4%. The unit cell parameters for Al0.916Cr0.084(acac)3 are smaller and the M - O distances are intermediate compared to those in the pure compounds, Crystal data: monoclinic, P21/c, a = 13.989(3), b = 7.539(2), c = 16.307(3) Å, β= 98.82(3)°, V = 1699.6(6), Z = 4.

KW - Acetylacetonate

KW - Aluminum

KW - Chromium

KW - Disorder

KW - Solid solution

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DO - 10.1023/A:1009554301560

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JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

SN - 1074-1542

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Molecular structure of Al_0.916Cr_0.084(acac)₃

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Keywords

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