TY - JOUR
T1 - Molybdenum carbonyl complexes of (dialkylamino)-diphenylphosphines (R2NPPh2)
AU - Atkinson, L. K.
AU - Smith, D. C.
PY - 1971/12/1
Y1 - 1971/12/1
N2 - Reactions of (dialkyamino)diphenylphosphines (R2NPPh2; R = Me, Et, Pr, Bu) with Mo(CO)6 and (C7H8)Mo(CO)4 have been studied, and the following complexes prepared: (R2NPPh2 Mo(CO)5 (R = Et, Pr, Bu); cis- and trans-(R2NPPh2)2Mo(CO)4 (R = Me, Et, Pr, Bu). IR, NMR and mass spectral data for these complexes are reported. Attempts to prepare dinuclear molybdenum complexes with both phosphorous and nitrogen as bridging ligand atoms yielded only phosphorous-bridged derivatives.
AB - Reactions of (dialkyamino)diphenylphosphines (R2NPPh2; R = Me, Et, Pr, Bu) with Mo(CO)6 and (C7H8)Mo(CO)4 have been studied, and the following complexes prepared: (R2NPPh2 Mo(CO)5 (R = Et, Pr, Bu); cis- and trans-(R2NPPh2)2Mo(CO)4 (R = Me, Et, Pr, Bu). IR, NMR and mass spectral data for these complexes are reported. Attempts to prepare dinuclear molybdenum complexes with both phosphorous and nitrogen as bridging ligand atoms yielded only phosphorous-bridged derivatives.
UR - http://www.scopus.com/inward/record.url?scp=0006151360&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)88408-9
DO - 10.1016/S0022-328X(00)88408-9
M3 - Article
AN - SCOPUS:0006151360
SN - 0022-328X
VL - 33
SP - 189
EP - 194
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2
ER -