Pyridinium oxidations of benzyl alcohol under microwave-assisted retro-ene conditions

Anton W. Jensen; John M. Moore; Mary Ellen V. Kimble; Alex P. Ausmus; Wendell L. Dilling

doi:10.1016/j.tetlet.2016.11.013

Pyridinium oxidations of benzyl alcohol under microwave-assisted retro-ene conditions

Anton W. Jensen, John M. Moore, Mary Ellen V. Kimble, Alex P. Ausmus, Wendell L. Dilling

https://www.cmich.edu/academics/colleges/college-science-engineering/departments-schools/chemistry-and-biochemistry

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3 Scopus citations

Abstract

Benzyl alcohol is oxidized to benzaldehyde when heated in sulfolane in the presence of N-benzylnicotinamide and N-benzylpyridinium salts. The oxidation is accelerated in the presence microwaves. Oxidations with related pyridiniums suggest that these oxidations could occur via retro-ene reactions.

Original language	English
Pages (from-to)	5636-5638
Number of pages	3
Journal	Tetrahedron Letters
Volume	57
Issue number	50
DOIs	https://doi.org/10.1016/j.tetlet.2016.11.013
State	Published - 2016

Keywords

Benzyl alcohol
NAD
Oxidation
Pyridinium

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10.1016/j.tetlet.2016.11.013

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title = "Pyridinium oxidations of benzyl alcohol under microwave-assisted retro-ene conditions",

abstract = "Benzyl alcohol is oxidized to benzaldehyde when heated in sulfolane in the presence of N-benzylnicotinamide and N-benzylpyridinium salts. The oxidation is accelerated in the presence microwaves. Oxidations with related pyridiniums suggest that these oxidations could occur via retro-ene reactions.",

keywords = "Benzyl alcohol, NAD, Oxidation, Pyridinium",

author = "Jensen, {Anton W.} and Moore, {John M.} and Kimble, {Mary Ellen V.} and Ausmus, {Alex P.} and Dilling, {Wendell L.}",

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T1 - Pyridinium oxidations of benzyl alcohol under microwave-assisted retro-ene conditions

AU - Jensen, Anton W.

AU - Moore, John M.

AU - Kimble, Mary Ellen V.

AU - Ausmus, Alex P.

AU - Dilling, Wendell L.

PY - 2016

Y1 - 2016

N2 - Benzyl alcohol is oxidized to benzaldehyde when heated in sulfolane in the presence of N-benzylnicotinamide and N-benzylpyridinium salts. The oxidation is accelerated in the presence microwaves. Oxidations with related pyridiniums suggest that these oxidations could occur via retro-ene reactions.

AB - Benzyl alcohol is oxidized to benzaldehyde when heated in sulfolane in the presence of N-benzylnicotinamide and N-benzylpyridinium salts. The oxidation is accelerated in the presence microwaves. Oxidations with related pyridiniums suggest that these oxidations could occur via retro-ene reactions.

KW - Benzyl alcohol

KW - NAD

KW - Oxidation

KW - Pyridinium

UR - http://www.scopus.com/inward/record.url?scp=84996508900&partnerID=8YFLogxK

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DO - 10.1016/j.tetlet.2016.11.013

M3 - Article

AN - SCOPUS:84996508900

SN - 0040-4039

VL - 57

SP - 5636

EP - 5638

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 50

ER -

Pyridinium oxidations of benzyl alcohol under microwave-assisted retro-ene conditions

Abstract

Keywords

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