TY - JOUR
T1 - Rhodium, palladium, and platinum complexes formed from 2,2,4-trimethylpent- 3-en-1-ol
AU - Atkinson, L. K.
AU - Smith, D. C.
PY - 1971
Y1 - 1971
N2 - 2,2,4-Trimethylpent-3-en-1-ol (Me2C:CH·CMe 2·CH2·OH) reacts with palladium(II) chloride to give π-enyl complexes, i.e. {[(CH2·CMe·CH) ·CMe2·CH2·OAc]PdCl}2 in aqueous acetic acid and {[(CH2·CMe·CH)·CMe 2·CH2·OH]PdCl}2 in dimethylformamide. No interaction between the palladium and acetate or hydroxy-functions is observed. Reaction with [Rh(CO)2Cl]2 in benzene gives the olefin complex [(Me2C:CH·CMe 2·CH2·OH)Rh(CO)Cl]2 in which the hydroxy-function is also co-ordinated to the metal. With platinum(II) chloride in dimethylformamide the alcohol yields an olefin complex [Me 2C:CH·CMe2·CH2·O· PtCl]2 which contains a Pt-O covalent bond. N.m.r. and i.r. data are given to support the structures proposed.
AB - 2,2,4-Trimethylpent-3-en-1-ol (Me2C:CH·CMe 2·CH2·OH) reacts with palladium(II) chloride to give π-enyl complexes, i.e. {[(CH2·CMe·CH) ·CMe2·CH2·OAc]PdCl}2 in aqueous acetic acid and {[(CH2·CMe·CH)·CMe 2·CH2·OH]PdCl}2 in dimethylformamide. No interaction between the palladium and acetate or hydroxy-functions is observed. Reaction with [Rh(CO)2Cl]2 in benzene gives the olefin complex [(Me2C:CH·CMe 2·CH2·OH)Rh(CO)Cl]2 in which the hydroxy-function is also co-ordinated to the metal. With platinum(II) chloride in dimethylformamide the alcohol yields an olefin complex [Me 2C:CH·CMe2·CH2·O· PtCl]2 which contains a Pt-O covalent bond. N.m.r. and i.r. data are given to support the structures proposed.
UR - http://www.scopus.com/inward/record.url?scp=37049139653&partnerID=8YFLogxK
U2 - 10.1039/J19710003592
DO - 10.1039/J19710003592
M3 - Article
AN - SCOPUS:37049139653
SN - 0022-4944
SP - 3592
EP - 3595
JO - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
JF - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
ER -