TY - GEN
T1 - Solution rheology of saline and polysaccharide systems
AU - Almeida, Ekmagage Don N.
AU - Rakesh, Leela
AU - Hirschi, Stanley
AU - Mueller, Anja
N1 - Funding Information:
This work is supported by both National Science Council of Taiwan (NSC89-2212-E006-093) and DARPA of U.S. Government, (DARPA-ARO #DAAH04-95-1-0093). The authors would like to thank Professor R. Ghodssi, Mr. S. Y. Lin and Mr. C. Y. Chen for their technical contributions.
PY - 2006
Y1 - 2006
N2 - The problem of the characterization of the solution properties of water soluble polymers is long-standing. These polymers tend to form aggregated supramolecular gels that are resistant to molecular dispersion. These materials are being widely used in a variety of industrial applications. Their principle functions are as rheological modifiers, where they thicken or gel solutions in products such as hair-care, detergents, air fresheners and foods; as flocculants for particle separation as applied to water clarification, sewage, and effluent treatment, and as stabilizers to control the properties of concentrated suspension and emulsions, for example in paints, pesticides, dyes, and pharmaceutical industries. Therefore it is important to understand their rheological properties under various operating conditions such as stress, strain, temperature etc, which will induce gelation. The rheological properties of starch gels of high concentration (up to 86% starch) have been investigated before [1]. In this paper we have investigated experimentally the shear viscosity and viscoelasticity properties of saline and polysaccharide suspensions at various low concentrations and pH at different temperatures using controlled stress and strain rheometers (Vilastic-3 and AR 2000). The data were then fitted with the power law and Cross model for low and higher concentrations respectively. The present results show that the viscosity/elasticity does not significantly change for low concentrations at different pH values. The maximum viscosity/elasticity was obtained around pH 5-7.4 at higher concentrations.
AB - The problem of the characterization of the solution properties of water soluble polymers is long-standing. These polymers tend to form aggregated supramolecular gels that are resistant to molecular dispersion. These materials are being widely used in a variety of industrial applications. Their principle functions are as rheological modifiers, where they thicken or gel solutions in products such as hair-care, detergents, air fresheners and foods; as flocculants for particle separation as applied to water clarification, sewage, and effluent treatment, and as stabilizers to control the properties of concentrated suspension and emulsions, for example in paints, pesticides, dyes, and pharmaceutical industries. Therefore it is important to understand their rheological properties under various operating conditions such as stress, strain, temperature etc, which will induce gelation. The rheological properties of starch gels of high concentration (up to 86% starch) have been investigated before [1]. In this paper we have investigated experimentally the shear viscosity and viscoelasticity properties of saline and polysaccharide suspensions at various low concentrations and pH at different temperatures using controlled stress and strain rheometers (Vilastic-3 and AR 2000). The data were then fitted with the power law and Cross model for low and higher concentrations respectively. The present results show that the viscosity/elasticity does not significantly change for low concentrations at different pH values. The maximum viscosity/elasticity was obtained around pH 5-7.4 at higher concentrations.
UR - http://www.scopus.com/inward/record.url?scp=84920629935&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:84920629935
SN - 0791837904
SN - 9780791837900
T3 - American Society of Mechanical Engineers, Materials Division (Publication) MD
BT - Proceedings of 2006 ASME International Mechanical Engineering Congress and Exposition, IMECE2006 - Materials
PB - American Society of Mechanical Engineers (ASME)
T2 - 2006 ASME International Mechanical Engineering Congress and Exposition, IMECE2006
Y2 - 5 November 2006 through 10 November 2006
ER -