Structure of Intercalated Cs in Zeolite ITQ-4: An Array of Metal Ions and Correlated Electrons Confined in a Pseudo-1D Nanoporous Host

V. Petkov, S. J.L. Billinge, T. Vogt, A. S. Ichimura, J. L. Dye

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Abstract

The presence of [Formula presented] ions in the pseudo-1D nanopores of zeolite ITQ-4, [Formula presented], is confirmed by x-ray diffraction and atomic pair distribution function analysis. Inside the nanopores the [Formula presented] ions are found to assemble in zigzag chains and thus form an extended, positively charged sublattice providing charge balance for a low-density electron gas also confined to the nanopores.

Original languageEnglish
JournalPhysical Review Letters
Volume89
Issue number7
DOIs
StatePublished - 2002

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