Syntheses of sugar poly(orthoesters) through reverse anomeric effect

Lingyao Li; Jun Wang; Melissa Obrinske; Ian Milligan; Kylie O'Hara; Lindsay Bitterman; Wenjun Du

doi:10.1039/c5cc00332f

Syntheses of sugar poly(orthoesters) through reverse anomeric effect

Lingyao Li, Jun Wang, Melissa Obrinske, Ian Milligan, Kylie O'Hara, Lindsay Bitterman, Wenjun Du

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

High molecular weight sugar poly(orthoesters) were synthesized through reverse anomeric effect (RAE). We demonstrated that when RAE-enabled promoters, such as 4-(dimethylamino)pyridine (DMAP), triphenylphosphine (TPP) or imidazole, were employed, efficient polymerizations were achieved, giving sugar poly(orthoesters) with molecular weights up to 18 kDa.

Original language	English
Pages (from-to)	6972-6975
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	32
DOIs	https://doi.org/10.1039/c5cc00332f
State	Published - Apr 25 2015

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abstract = "High molecular weight sugar poly(orthoesters) were synthesized through reverse anomeric effect (RAE). We demonstrated that when RAE-enabled promoters, such as 4-(dimethylamino)pyridine (DMAP), triphenylphosphine (TPP) or imidazole, were employed, efficient polymerizations were achieved, giving sugar poly(orthoesters) with molecular weights up to 18 kDa.",

author = "Lingyao Li and Jun Wang and Melissa Obrinske and Ian Milligan and Kylie O'Hara and Lindsay Bitterman and Wenjun Du",

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AU - Li, Lingyao

AU - Wang, Jun

AU - Obrinske, Melissa

AU - Milligan, Ian

AU - O'Hara, Kylie

AU - Bitterman, Lindsay

AU - Du, Wenjun

PY - 2015/4/25

Y1 - 2015/4/25

N2 - High molecular weight sugar poly(orthoesters) were synthesized through reverse anomeric effect (RAE). We demonstrated that when RAE-enabled promoters, such as 4-(dimethylamino)pyridine (DMAP), triphenylphosphine (TPP) or imidazole, were employed, efficient polymerizations were achieved, giving sugar poly(orthoesters) with molecular weights up to 18 kDa.

AB - High molecular weight sugar poly(orthoesters) were synthesized through reverse anomeric effect (RAE). We demonstrated that when RAE-enabled promoters, such as 4-(dimethylamino)pyridine (DMAP), triphenylphosphine (TPP) or imidazole, were employed, efficient polymerizations were achieved, giving sugar poly(orthoesters) with molecular weights up to 18 kDa.

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Syntheses of sugar poly(orthoesters) through reverse anomeric effect

Abstract

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