The preparation and isomerisation of trans-dicarbonylbis-1,2-bis(diphenylphosphino)ethane]molybdenum(0)

L. K. Holden; A. H. Mawby; D. C. Smith; R. Whyman

doi:10.1016/S0022-328X(00)82076-8

The preparation and isomerisation of trans-dicarbonylbis-1,2-bis(diphenylphosphino)ethane]molybdenum(0)

L. K. Holden, A. H. Mawby, D. C. Smith, R. Whyman

Research output: Contribution to journal › Article › peer-review

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Abstract

The reaction of trans-Mo(N₂)₂(Dppe)₂ (Dppe = Ph₂PCH₂CH₂PPh₂) with carbon monoxide gives, initially, the previously unknown trans-Mo(CO)₂(Dppe)₂, which isomerises in solution to the well-known cis isomer. The reaction was followed by IR spectroscopy under carbon monoxide pressure.

Original language	English
Pages (from-to)	343-345
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	55
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)82076-8
State	Published - Jul 16 1973
Externally published	Yes

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title = "The preparation and isomerisation of trans-dicarbonylbis-1,2-bis(diphenylphosphino)ethane]molybdenum(0)",

abstract = "The reaction of trans-Mo(N2)2(Dppe)2 (Dppe = Ph2PCH2CH2PPh2) with carbon monoxide gives, initially, the previously unknown trans-Mo(CO)2(Dppe)2, which isomerises in solution to the well-known cis isomer. The reaction was followed by IR spectroscopy under carbon monoxide pressure.",

author = "Holden, {L. K.} and Mawby, {A. H.} and Smith, {D. C.} and R. Whyman",

year = "1973",

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T1 - The preparation and isomerisation of trans-dicarbonylbis-1,2-bis(diphenylphosphino)ethane]molybdenum(0)

AU - Holden, L. K.

AU - Mawby, A. H.

AU - Smith, D. C.

AU - Whyman, R.

PY - 1973/7/16

Y1 - 1973/7/16

N2 - The reaction of trans-Mo(N2)2(Dppe)2 (Dppe = Ph2PCH2CH2PPh2) with carbon monoxide gives, initially, the previously unknown trans-Mo(CO)2(Dppe)2, which isomerises in solution to the well-known cis isomer. The reaction was followed by IR spectroscopy under carbon monoxide pressure.

AB - The reaction of trans-Mo(N2)2(Dppe)2 (Dppe = Ph2PCH2CH2PPh2) with carbon monoxide gives, initially, the previously unknown trans-Mo(CO)2(Dppe)2, which isomerises in solution to the well-known cis isomer. The reaction was followed by IR spectroscopy under carbon monoxide pressure.

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U2 - 10.1016/S0022-328X(00)82076-8

DO - 10.1016/S0022-328X(00)82076-8

M3 - Article

AN - SCOPUS:0040364196

SN - 0022-328X

VL - 55

SP - 343

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

The preparation and isomerisation of trans-dicarbonylbis-1,2-bis(diphenylphosphino)ethane]molybdenum(0)

Abstract

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